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Kineties and Mechanisms of the Gas-Phase Reactions

By Atkinsoll, Roger

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Book Id: WPLBN0000658302
Format Type: PDF eBook
File Size: 5.03 MB.
Reproduction Date: 2005
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Title: Kineties and Mechanisms of the Gas-Phase Reactions  
Author: Atkinsoll, Roger
Volume:
Language: English
Subject: Technology., Reference materials, Technology and literature
Collections: Techonology eBook Collection
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Atkinsoll, R. (n.d.). Kineties and Mechanisms of the Gas-Phase Reactions. Retrieved from http://worldebooklibrary.com/


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Technical Reference Publication

Excerpt
Introduction: Measurements made during the 13 years have shown the nitrate (NOS) radical to be present in the nighttime stratosphere and troposphere.-20 In the lower troposphere over continental areas the reported NO3 radical mixing ratios range from < 2 parts-per-trillion (ppt). The NO3 radical mixing ratios in marine air masses in the troposphere are low, with upper limits of c 0.5 ppt being reported by Platt and Perne.

Table of Contents
Contents 1. Introduction ................................ 1.1. Experimental Techniques .............. l.l.a. Absolute Rate Measurements .... 1.l.b. Relative Rate Measurements .... 1.2. Product Studies ....................... 2 . Kinetic, Mechanistic, and Product Data Obtained ...................................... 2.1. Alkanes ............................... 2.1.a. Kinetics and Mechanisms ........ (1) Methane ....................... (2) 2,3-Dimethylbutane ............. (3) n -Heptane ..................... (4) Other Alkanes ................. 2.2. Haloalkanes ........................... 2.2.a. Kinetics and Mechanisms ........ 2.3. Alkenes ............................... 2.3.a. Mnetics ......................... (1) Ethene ........................ (2) Propene and Propene-d6 ........ (3) I-Butene .................... .. . (4) 2-Methylproperme ............... (5) cis-2-Butene ................... (6) tram-2-Butene ................. (7) 2-Methyl-2-butene .............. (8) 2,3-Dimethyl- 2-butene .......... (9) 1,3 -Butadiene .................. 01991 by the U.S. Secretary of Commerce on behalf of the Unitcd States . This copyright is assigncd to the American Institute of Physics and the American Chemical Society . Reprints available from ACS; see Reprints List at back of issue . (10) 2-Methyl- I. 3-butadiene (isoprene) ..................... (11) 2.3.Dimethyl.1.3.butadiene ..... (12) 1.3 . and 1.4.Cyclohexadiene .... (13) aBinene ...................... (14) p-P' inene ...................... (15) A3-Carene and d-Limonene .... (16) Other Dienes. Trienes and Cycloalkenes. ................. 2.3.b. Mechanism ..................... 2.4. Haloalkenes ........................... 2.4.a. Kinetics and Mechanisms ........ (1) Vinyl chloride ...................... 2.5. Alkynes ............................... 2.5.a. Kinetics and Mechanisms ......... (1) Acetylene ...................... (2) Bropyne ....................... 2.6. Oxygen-Containing Organic Compounds 2.6.a. Kinetics and Mechanisms ........ (1) Formaldehyde.. ................ (2) Acetaldehyde .................. (3) Methanol ...................... (4) Other Oxygen Containing Organic Compounds .............. 2.7.Sulfur.C~ntaining Organic Compounds ... 2.7.a. Kinetics ........................ (1) Methanethiol ................... (2) Dimethyl sulfide ................ (3) Dimethyl disulfide .............. (4) Thiophene ..................... (5) Ethawethhol .................... 2.7.b. Mechanism .....................

 

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