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Oiabilitiess F Solids and Liquids of Low Volatility in Supercritical Carbon

By Bartle, K. D.

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Book Id: WPLBN0000657791
Format Type: PDF eBook
File Size: 3.23 MB.
Reproduction Date: 2005
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Title: Oiabilitiess F Solids and Liquids of Low Volatility in Supercritical Carbon  
Author: Bartle, K. D.
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Language: English
Subject: Technology., Reference materials, Technology and literature
Collections: Techonology eBook Collection
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Bartle, K. (n.d.). Oiabilitiess F Solids and Liquids of Low Volatility in Supercritical Carbon. Retrieved from http://worldebooklibrary.com/


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Technical Reference Publication

Table of Contents
Contents 1.1. Background .................................................. 1.2. Scope ............................................................ 1.3. Phase Behavior for Involatile Solutes .......... 1.4. Method Used for Correlation of Solubilities 1.5. Estimation of Solubility Using the Correlations ....................... , .................................. 2. Experimental Methods ......................................... 2.1. Gravimetric Methods ................................... 2.2. Chromatographic Methods .......................... 2.3. Spectroscopic Methods ................................ 2.4. Miscellaneous Methods ................................ 3. Review and Correlation of Pubhshed Experimental Results ............................................................. 4. Acknowledgments ................................................ 5. References ............................................................ List of Tables 1. Constants a, b, and a for naphthalene and phenanthrene for isotherms published by various authors ................................................................... 2. Published solubility data in carbon dioxide ....... 3. Alphabetical index to the compounds in Fig. 7 . 714 4. Correlation constants A and B in Eq. (4) ob- 714 tained by fitting literature solubility data ........... 714 5. Densities of pure carbon dioxide in moles dm- 714 from the Ely equation of stateI6 ......................... 717 List of Figures 720 721 1. p-T projections of schematic phase diagrams for 72 1 mixtures of carbon dioxide and a solute of low 725 volatility ............................................................... 725 2. x-T cross sections through schematic phase dia- 725 grams for mixtures of carbon dioxide and a solute of low volatility .................................................... 726 3. Features which can occur in solubility isotherms 755 4. Plots of the constants A and A ' vs 1/T for naph- 755 thalene .................................................................. 5. Comparison of the experimental results for naphthalene and the predictions, shown as curves, of an approximate estimation method described in the text ................................................................. 6. Schematic diagram of an apparatus for the gravi- 718 metric method ...................................................... 722 7. Published tabulated data for solubilities in carbon 727 dioxide, shown as points, and curves obtained by fitting an isothermto Eq. (4). The constants used @ 1991 by the U.S. Secretary of Commerce on behalf of the United States. This copylight is assigned to the American Institute of Physics and the for the correlation curve shown are given in Table American Chemical Societv. 4. An alphabetical index to the compounds in the available from ACS; see Reprints List at back of issue. figure is given in Table 3 ......................................

 

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